Date of Award
2012
Degree Type
Open Access Dissertation
Degree Name
Computational Science Joint PhD with San Diego State University, PhD
Program
School of Mathematical Sciences
Advisor/Supervisor/Committee Chair
Arlette R. C. Baljon
Dissertation or Thesis Committee Member
Andrew L. Cooksy
Dissertation or Thesis Committee Member
Peter Salamon
Dissertation or Thesis Committee Member
Allon Percus
Terms of Use & License Information
Rights Information
© 2012 Joris Billen
Keywords
Complex networks, Gels, Molecular Dynamics Simulations, Polymer Physics, Rheology, Telechelic Polymers
Subject Categories
Biological and Chemical Physics | Computer Sciences | Physics
Abstract
Telechelic associating polymer networks consist of polymer chains terminated by endgroups that have a different chemical composition than the polymer backbone. When dissolved in a solution, the endgroups cluster together to form aggregates. At low temperature, a strongly connected reversible network is formed and the system behaves like a gel. Telechelic networks are of interest since they are representative for biopolymer networks (e.g. F-actin) and are widely used in medical applications (e.g. hydrogels for tissue engineering, wound dressings) and consumer products (e.g. contact lenses, paint thickeners).
In this thesis such systems are studied by means of a molecular dynamics/Monte Carlo simulation. At first, the system in rest is studied by means of graph theory. The changes in network topology upon cooling to the gel state, are characterized. Hereto an extensive study of the eigenvalue spectrum of the gel network is performed. As a result, an in-depth investigation of the eigenvalue spectra for spatial ER, scale-free, and small-world networks is carried out. Next, the gel under the application of a constant shear is studied, with a focus on shear banding and the changes in topology under shear. Finally, the relation between the gel transition and percolation is discussed.
DOI
10.5642/cguetd/51
Recommended Citation
Billen, Joris. (2012). Simulated Associating Polymer Networks. CGU Theses & Dissertations, 51. https://scholarship.claremont.edu/cgu_etd/51. doi: 10.5642/cguetd/51
Comments
Fourth Committee Member: Adam Landsberg