Synthesis and Characterization of a Novel Platinum Ligand Complex ((κ-N,C,N- 2,6-bis(diethylaminomethyl)phenyl)(4- tert-butylphenyl) platinum(II))

Author

Carly Roleder, Claremont McKenna CollegeFollow

Graduation Year

2018

Date of Submission

12-2017

Document Type

Open Access Senior Thesis

Degree Name

Bachelor of Arts

Department

Chemistry

Second Department

Biochemistry

Reader 1

Nancy Williams

Reader 2

Kersey Black

Terms of Use & License Information

Terms of Use for work posted in Scholarship@Claremont.

Rights Information

© 2017 Carly W Roleder

Abstract

A novel platinum ligand complex (NCN)PtAr, ((κ-N,C,N- 2,6-bis (diethylaminomethyl)phenyl)(4- tert-butylphenyl) platinum(II)), was synthesized. A reaction of 1-Bromo-4-tert-butylbenzene Grignard with (NCN)PtCl, (where NCN = 2,6-bis(diethylaminomethyl)phenyl) yielded the (NCN)PtAr (where Ar = 4-tert­-butylphenyl). The product was then characterized with NMR spectra through ¹H NMR, ¹³C NMR, COSY, HSQC, and HMBC to verify it structure.

Recommended Citation

Roleder, Carly, "Synthesis and Characterization of a Novel Platinum Ligand Complex ((κ-N,C,N- 2,6-bis(diethylaminomethyl)phenyl)(4- tert-butylphenyl) platinum(II))" (2018). CMC Senior Theses. 1732.
https://scholarship.claremont.edu/cmc_theses/1732